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Erbium (Er) - Atomic Structure & Properties

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Erbium Er Atomic Structure Chemical Properties Lanthanides JEE NEET Chemistry

Atomic Model Details

Erbium (Er) is a lanthanide element.

  • Atomic Number (Z): 68
  • Atomic Mass (A): 167.259 u
  • Protons: 68
  • Electrons: 68 (in a neutral atom)
  • Neutrons: Approximately 99 (average for natural isotopes; e.g., the most abundant isotope $^\{166\}$Er has 98 neutrons).
  • Atomic Size:
    • Metallic Radius (12-coordinate): 178 pm
    • Ionic Radius (Er³⁺): 89 pm

Electronic Configuration & Shell Diagram

  • Electronic Configuration: [Xe] 4f¹² 6s²
    • This configuration indicates that after the stable noble gas core of Xenon (Xe), there are 12 electrons in the 4f subshell and 2 electrons in the 6s subshell. The 4f electrons are inner-shell electrons and contribute significantly to shielding.
  • Shell-wise Electron Distribution:
    • K-shell (n=1): 2 electrons (1s²)
    • L-shell (n=2): 8 electrons (2s² 2p⁶)
    • M-shell (n=3): 18 electrons (3s² 3p⁶ 3d¹⁰)
    • N-shell (n=4): 30 electrons (4s² 4p⁶ 4d¹⁰ 4f¹²)
    • O-shell (n=5): 8 electrons (5s² 5p⁶)
    • P-shell (n=6): 2 electrons (6s²)

Erbium, like other lanthanides, exhibits specific trends influenced by the filling of its 4f subshell.

  • Ionization Enthalpy:
    • First Ionization Enthalpy (IE₁): 589.3 kJ/mol
    • Second Ionization Enthalpy (IE₂): 1150 kJ/mol
    • Third Ionization Enthalpy (IE₃): 2195 kJ/mol
    • Trend: Relatively low compared to main group elements, typical for metals. The successive ionization enthalpies increase as electrons are removed from the positively charged ion.
  • Electronegativity (Pauling Scale): 1.24
    • Trend: Low, reflecting its metallic character and tendency to lose electrons rather than gain them.
  • Electron Gain Enthalpy:
    • Not readily available; expected to be positive or near zero, indicating a low tendency to gain electrons due to its metallic character and stable 4f¹² 6s² configuration.
  • Atomic Radius:
    • Metallic radius generally decreases across the lanthanide series (Lanthanoid Contraction) due to poor shielding by the 4f electrons, leading to a stronger attraction between the nucleus and the outer electrons.

Key Physical Properties

  • Density: 9.066 g/cm³ (at 25 °C)
  • State: Solid (at 25 °C and 1 atm)
  • Color: Silvery-white metal with a bright metallic luster. It tarnishes slowly in air.
  • Melting Point (MP): 1529 °C (1802 K)
  • Boiling Point (BP): 2868 °C (3141 K)