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Holmium (Ho) - Atomic Structure & Properties
By Periodic Table India
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Holmium Ho Atomic Structure Periodic Properties Chemistry Lanthanide JEE NEET CBSE ICSE
Atomic Model Details
Holmium (Ho) is a rare earth element, specifically a lanthanide.
- Atomic Symbol: Ho
- Atomic Number (Z): 67
- Atomic Mass (A): 164.93033 u (for the most stable and naturally abundant isotope, ¹⁶⁵Ho)
- Number of Protons: 67 (equal to atomic number)
- Number of Electrons: 67 (in a neutral atom)
- Number of Neutrons: 98 (for ¹⁶⁵Ho: Mass Number - Atomic Number = 165 - 67)
- Atomic Radius (Metallic): 177 pm
Electronic Configuration & Shell Diagram
The electronic configuration dictates the chemical behavior of an element.
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Electronic Configuration:
[Xe] 4f¹¹ 6s²- This indicates that Holmium has the electron configuration of Xenon (Xe) followed by 11 electrons in the 4f subshell and 2 electrons in the 6s subshell.
- Expanded Configuration:
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 4f¹¹ 5s² 5p⁶ 6s²
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Shell-wise Electron Distribution:
- K-shell (n=1): 2 electrons (1s²)
- L-shell (n=2): 8 electrons (2s² 2p⁶)
- M-shell (n=3): 18 electrons (3s² 3p⁶ 3d¹⁰)
- N-shell (n=4): 29 electrons (4s² 4p⁶ 4d¹⁰ 4f¹¹)
- O-shell (n=5): 8 electrons (5s² 5p⁶)
- P-shell (n=6): 2 electrons (6s²)
Periodic Trends
Holmium’s position as a lanthanide in the f-block influences its periodic trends.
Ionization Enthalpy
- First Ionization Enthalpy (IE₁): Approximately 581 kJ/mol
- Second Ionization Enthalpy (IE₂): Approximately 1140 kJ/mol
- Third Ionization Enthalpy (IE₃): Approximately 2161 kJ/mol
- Trend: Lanthanides generally have relatively low ionization enthalpies due to the shielding effect of the inner 4f electrons and their relatively large atomic size. IE values generally show a slight increase across the lanthanide series due to the lanthanide contraction, which causes a gradual decrease in atomic radii and a corresponding increase in effective nuclear charge.
Electronegativity
- Pauling Electronegativity: 1.23
- Trend: Holmium is highly electropositive, characteristic of metals, especially those in the lanthanide series. Its electronegativity is low, indicating a strong tendency to lose electrons rather than gain them.
Electron Gain Enthalpy
- Value: Data not precisely reported for Holmium; however, for most metals, especially electropositive ones like lanthanides, the electron gain enthalpy is either slightly positive or close to zero, meaning they do not readily accept electrons.
Atomic Radius
- Metallic Radius: 177 pm
- Trend: As a lanthanide, Holmium exhibits lanthanide contraction. This phenomenon refers to the steady decrease in the atomic and ionic radii of the lanthanide elements with increasing atomic number, due to the poor shielding effect of the 4f electrons. Consequently, Holmium’s atomic radius is slightly smaller than expected if this contraction did not occur, and it is generally smaller than preceding lanthanides.
Key Physical Properties
Holmium is a silvery-white, relatively soft, and malleable metal.
- Density: 8.79 g/cm³ (at 20°C)
- State at STP: Solid
- Color: Silvery-white
- Melting Point: 1474 °C (1747 K)
- Boiling Point: 2700 °C (2973 K)