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Lithium (Li) - Atomic Structure & Chemical Properties

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Chemistry Revision Lithium s-block Periodic Table Atomic Structure JEE NEET CBSE ICSE

Atomic Model Details of Lithium (Li)

  • Element Symbol: Li
  • Atomic Number (Z): 3
    • Number of Protons: 3
    • Number of Electrons: 3 (in a neutral atom)
  • Mass Number (A): Approximately 7 (for the most common isotope, Lithium-7)
    • Number of Neutrons: 4 (Mass Number - Atomic Number = 7 - 3)
  • Atomic Size (Metallic Radius): 152 pm

Electronic Configuration & Shell Diagram Representation

  • Electronic Configuration: 1s² 2s¹
  • Shell Diagram Representation:
    • K-shell (1st shell): Contains 2 electrons (fully filled).
    • L-shell (2nd shell): Contains 1 electron (valence electron).
    • This configuration indicates that Lithium has one electron in its outermost shell (valence shell), making it highly reactive and prone to losing this electron to form a +1 ion.
  • First Ionization Enthalpy (IE₁): 520.2 kJ/mol
    • This is the energy required to remove the single valence electron. Being an alkali metal, Lithium has a relatively low first ionization enthalpy compared to elements in the same period, but higher than other alkali metals below it in Group 1.
  • Electronegativity (Pauling Scale): 0.98
    • Lithium has a low electronegativity, indicating its tendency to lose electrons rather than attract them in a chemical bond.
  • Electron Gain Enthalpy: +59.6 kJ/mol
    • The positive value indicates that energy must be supplied to add an electron to a neutral Lithium atom, signifying its metallic character and low tendency to accept electrons.
  • Atomic Radius: 152 pm
    • As the first element in Group 1, Lithium has the smallest atomic radius among the alkali metals.

Key Physical Properties of Lithium (Li)

  • Density: 0.534 g/cm³ (at 20°C)
    • Lithium is the lightest known metal.
  • State at Standard Temperature and Pressure (STP): Solid
  • Color: Silvery-white (when freshly cut, rapidly tarnishes in air to a dull grey or black due to oxide formation).
  • Melting Point: 180.5 °C
    • Lithium has a relatively low melting point for a metal, but it is the highest among the alkali metals.
  • Boiling Point: 1342 °C