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Neon (Ne) - Atomic Structure & Chemical Properties

By Periodic Table India
CBSE / JEE Prep Notes
Neon Noble Gas Atomic Structure Periodic Properties Chemistry

Atomic Model

Neon (Ne) is the tenth element in the periodic table, belonging to Group 18 (Noble Gases).

  • Atomic Number (Z): 10
    • Number of Protons: 10
    • Number of Electrons: 10 (in a neutral atom)
  • Mass Number (A): Approximately 20 (for the most abundant isotope, $^{20}$Ne).
    • Number of Neutrons: 10 (for $^{20}$Ne)
  • Atomic Radius:
    • Van der Waals Radius: Approximately 154 pm (picometers)

Electronic Configuration & Shell Diagram

Neon possesses a highly stable electron configuration, which accounts for its inertness.

  • Electronic Configuration: $1s^2 2s^2 2p^6$
    • This can also be represented as $[He] 2s^2 2p^6$, where $[He]$ represents the electron configuration of Helium.
  • Shell Distribution (Shell Diagram Representation):
    • K-shell (n=1): Contains 2 electrons ($1s^2$).
    • L-shell (n=2): Contains 8 electrons ($2s^2 2p^6$). This is a completely filled outermost shell (octet), signifying high stability.

Due to its complete octet and high stability, Neon exhibits distinct periodic trends.

  • First Ionization Enthalpy ($\Delta H_{i1}$):
    • Value: Approximately 2080.7 kJ/mol
    • Explanation: Extremely high due to its stable, completely filled valence shell, making it very difficult to remove an electron.
  • Electronegativity:
    • Value: Not typically assigned or considered zero on most scales (e.g., Pauling scale) due to its inertness and inability to form compounds. If theoretically extrapolated, it would be very high.
    • Explanation: Does not form chemical bonds, therefore its tendency to attract electrons in a covalent bond is not relevant.
  • Electron Gain Enthalpy ($\Delta H_{eg}$):
    • Value: Approximately +29 kJ/mol (endothermic)
    • Explanation: Highly positive, indicating that energy must be supplied to add an electron to a neutral Neon atom. This is because adding an electron would disrupt its stable, filled valence shell, leading to a higher energy state.
  • Atomic Radius:
    • Value: Van der Waals radius ~154 pm.
    • Explanation: Generally, van der Waals radii are used for noble gases as they do not form covalent bonds. This value is relatively small compared to other elements in its period when considering only van der Waals radii within the same period (Group 18 elements have the largest van der Waals radii in their respective periods).

Key Physical Properties

Neon is a colorless, odorless, and tasteless noble gas.

  • Density:
    • At STP (Standard Temperature and Pressure): Approximately 0.900 g/L (0.000900 g/cm³)
  • State at STP: Gas
  • Color: Colorless
    • However, when excited in a vacuum discharge tube, it emits a characteristic brilliant reddish-orange light, used in neon signs.
  • Melting Point: -248.6 °C (or 24.55 K)
  • Boiling Point: -246.1 °C (or 27.07 K)