Ruthenium (Ru) - Revision Guide
Atomic Model Details
Ruthenium (Ru) is a transition metal element. Its atomic structure defines its fundamental chemical and physical characteristics.
Fundamental Particles
- Atomic Symbol: Ru
- Atomic Number (Z): 44 (Indicates 44 protons in the nucleus)
- Average Atomic Mass: 101.07 u (unified atomic mass units)
- Protons: 44
- Electrons: 44 (in a neutral Ruthenium atom)
- Neutrons: Approximately 57 (Calculated as Average Atomic Mass - Atomic Number; for common isotope Ru-102, it is 102 - 44 = 58 neutrons)
Atomic Size
- Covalent Radius: ~134 picometers (pm)
Electronic Configuration & Shell Diagram
The arrangement of electrons in an atom’s shells and subshells dictates its chemical behavior.
Electronic Configuration
Ruthenium exhibits an anomalous electronic configuration due to the stability associated with half-filled or completely filled d-orbitals.
- Condensed Configuration:
[Kr] 4d⁷ 5s¹ - Full Configuration:
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d⁷ 5s¹
Shell Diagram Representation (Textual Explanation)
In a neutral Ruthenium atom:
- K-shell (n=1): 2 electrons (
1s²) - L-shell (n=2): 8 electrons (
2s² 2p⁶) - M-shell (n=3): 18 electrons (
3s² 3p⁶ 3d¹⁰) - N-shell (n=4): 15 electrons (
4s² 4p⁶ 4d⁷) - O-shell (n=5): 1 electron (
5s¹) The outermost shell (valence shell) is the 5th shell, containing 1 electron in the5ssubshell, and the penultimate4dsubshell is partially filled with 7 electrons, characteristic of a transition metal.
Periodic Trends
Ruthenium’s position in Group 8 and Period 5 of the periodic table influences its periodic properties.
Ionization Enthalpy
The energy required to remove the most loosely bound electron from an isolated gaseous atom.
- First Ionization Enthalpy: 710.2 kJ/mol (Energy required to remove the first electron)
- Second Ionization Enthalpy: 1620 kJ/mol
Electronegativity
A measure of the tendency of an atom to attract a shared pair of electrons.
- Pauling Scale: 2.2
Electron Gain Enthalpy
The energy change when an electron is added to a neutral gaseous atom to form a negative ion.
- Electron Gain Enthalpy: -97 kJ/mol (Exothermic process, indicating a tendency to accept an electron, though less pronounced than halogens)
Atomic Radius
The size of an atom, typically measured as covalent or metallic radius.
- Covalent Radius: ~134 pm
Key Physical Properties
Ruthenium is a hard, brittle, silvery-white transition metal.
- Density: 12.45 g/cm³ (at 20°C)
- State at STP (Standard Temperature and Pressure): Solid
- Color: Silvery-white, lustrous
- Melting Point: 2334 °C
- Boiling Point: 4150 °C